Hi Baemorth,
Congratulations on taking the plunge with the painting!
One thing I would like to add to all the good advice above is that there's always a trade-off between how good the mini looks and the amount of time you spend on it. There are some things you can do to maximise the appearance of the miniature without spending too much time. A lot of painting seems to be a matter of taste and what you feel suits your painting style, so don't take any of my comments as gospel!
My aim is to to paint to a good tabletop standard, rather than competition or display standard, and have found the following helpful:
- I brush on my undercoat, mainly because I have nowhere indoors to spray the minis and it's more sociable (I paint sat next to my wife on the sofa with a tray on my lap).
- I go with a dark undercoat (e.g black) and then try to avoid painting over this with the base coat in the creases of the model. I know people who also use grey and white as the undercoat instead though. I find that the neater you can get your base coat of colours, the better! I also try to leave a thin line of black between where coulours meet.
- Good lighting is essential, although expensive daylight bulbs are not. Who plays the game outdoors anyway

I use a pedestal lamp with a reading light positioned over my shoulder
- I hate buying from GW these days, but have only good things to say about their foundation range of paints and the washes, although the Devlan Mud has a really offensive smell. Once the basecoat is done I liberally apply a coat of Devlan mud as a shade. I think the Army Painter dip is similar, maybe a bit less strong tone. I also use the vallejo Game Colour range which I can say has been good.
- Once the shade is dry, I repaint a watered down base coat again, leaving it darker in the recesses. Once done, I then highlight with a ligher shade.
- Don't forget to tidy/paint the base - this makes the model look so much sharper!
- As I paint mainly metal figures (and mainly for bloodbowl which puts a lot of wear and tear on the models) I brush on a layer of Vallejo Matt varnish to preserve the paint. I've had bad experiences with spary on varnishes leaving the models looking frosty.
Cheers,
Steven
Hope this helps!
Spiky